Devil's Food Cake with Fluffy Frosting

Devil's Food Cake with Fluffy Frosting was pinched from <a href="http://www.marthastewart.com/903157/devils-food-cake-fluffy-frosting" target="_blank">www.marthastewart.com.</a>
INGREDIENTS
3 sticks unsalted butter, room temperature, plus more for pans
1 cup unsweetened cocoa powder, plus more for pans
1 cup boiling water
1 cup sour cream
3 cups all-purpose flour (spooned and leveled)
3/4 teaspoon fine salt
1 teaspoon baking powder
1 teaspoon baking soda
3 3/4 cups sugar, divided
4 large eggs, plus 5 large egg whites, room temperature, divided
5 teaspoons pure vanilla extract, divided
1 tablespoon corn syrup
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